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2.1 Hydrogen and different Hydrogen Production models

2.1 Hydrogen and different Hydrogen Production models

This chapter provides an overview of hydrogen and its role in mitigating climate change. It covers different methods of hydrogen production and compares their CO2 emissions. The importance of green hydrogen in the energy transition and greenhouse gas reduction is discussed, along with the basics of generating electricity from renewable sources for green hydrogen production. The chapter also explores technical details of green hydrogen production via electrolysis, including comparisons of electrolysis technologies and examples of electrolysers in operation or planned in Northern Germany.

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Properties and characteristics

Hydrogen is the first element of the periodic table of elements and thus has the lowest atomic mass of all elements. Therefore, when planning on using hydrogen as an energy carrier, it has to be taken into account, that the handling of hydrogen is different compared to other gases or substances with respect to its properties and very own characteristics. Some of those are stated as a short overview in the table below.

Table of hydrogen properties and characteristics
Hydrogen properties and characteristics by Fabian Carels and Lisa Karies (CC BY-SA)

Whereas the high gravimetric energy density is advantageous regarding hydrogen use as an energy carrier, the very low volumetric energy density poses some difficulties, especially with regard to storage and transport. For better understanding of the dimensions, the following figure shows the gravimetric and volumetric energy densities of different energy carriers compared to hydrogen.
 Comparision of gravimetric and volumetric energy densities of different energy carriers in a statistic
Comparision of gravimetric and volumetric energy densities of different energy carriers by Fabian Carels and Lisa Karies (CC BY-SA)

 

 

The figure shows that liquid energy carries, such as diesel fuel or petrol (= gasoline), have a significantly larger volumetric energy density compared to hydrogen. Due to the logarithmic scaling of the y-axis, the difference between hydrogen and the other energy carriers in terms of volumetric energy density is actually even higher than it appears at first glance at the diagram. At ambient pressure, even the volumetric energy density of natural gas exceeds that of hydrogen by a factor of about 3. Thus, for hydrogen use either very large tank volumes are needed or an increase of hydrogen’s volumetric energy density is necessary via compression or even liquidisation. More details regarding these challenges will be provided in chapter 3. On the other hand, the figure also shows that hydrogen clearly outperforms other energy carriers in terms of gravimetric energy density.

 

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