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2. Resources for the bioeconomy

Website: Hamburg Open Online University
Kurs: Process engineering for the bioeconomy
Buch: 2. Resources for the bioeconomy
Gedruckt von: Gast
Datum: Montag, 21. Juli 2025, 20:02

Beschreibung

This book provides an overview of the diverse raw material base of the bioeconomy.

2. Resources for the bioeconomy

 

The basics

As the name suggests, the bioeconomy is based on organic raw materials derived from animals, plants, fungi, algae or microorganisms. This so-called biomass, as well as its remnants and waste, can be used to generate energy or new products. This chapter provides an overview of the diverse raw material base of the bioeconomy.

 

 

Overview of bioresources by Anne Rödl (CC BY), adaptation by Jana Schultz



First of all, the most important basic resources, without which there would be no plant or animal production:
  • Land
  • Water
  • Nutrients

Furthermore, bio-based products cannot be produced on a large scale without the use of human labor, technology and infrastructure. Humans have increased the yield of plants through breeding and further increased it through mechanical cultivation. Without these resources, the large number of people on earth could not be fed and supplied with products.

What you should know
  • Four crops alone (sugar cane, maize, cereals and rice) produce over half of the world's agricultural harvest
  • In the USA, the largest bioethanol producer, bioethanol is mainly produced from maize
  • The most important oil plant with the highest yields per unit area is the oil palm

2.1 Plant origin

Plants break down organic substances (carbohydrates, fats, proteins) from carbon dioxide and water through photosynthesis with the help of sunlight. As primary producers, plants are therefore the most important source of raw materials in the bioeconomy. Plant parts and their fruits are mainly used as food and animal feed, but are also processed to produce building materials, textiles, energy, pharmaceuticals and paper.
 
The 10 crops with the largest harvested quantities worldwide are sugar cane, maize, wheat, rice, oil palms, potatoes, soybeans, cassava and vegetables (FAOSTAT 2022). Sugar cane, maize, rice and wheat account for half of global primary agricultural production. These crops are mainly grown as food sources. However, sugar cane, maize, palm oil, soy and wheat are also increasingly being used as raw materials for fuel production. Overall, the global cultivation of primary crops, oil plants, fruit and vegetables has risen sharply in the last twenty years (FAO 2022). 

 

Agricultural Plantation

Agricultural crops containing sugar and starch make up the majority of crops grown worldwide. The four crops sugar cane, maize, rice and wheat produce half of the global harvest. In 2021, 9.5 billion tons of crops were produced worldwide (FAO 2022). The following diagram shows the distribution of the various crop groups.
 


Agricultural production by Anne Rödl, adopted by Jana Schultz (CC BY)
 
In Germany, agriculture is practised on around 46% of the 35.8 million hectares of total land (FNR 2021). Crops for industrial or energy purposes are grown on around 16% of this agricultural land. That is around 2.6 million hectares.
 
Tortendiagramme zur Flächennutzung in Deutschland
Land use in Germany by Anne Rödl (CC BY)
 
The majority of the 2.6 million hectares of land under cultivation for industrial and energy crops is used to grow maize for the production of biogas. However, large areas are also used to cultivate plants for the production of biodiesel and bioethanol (FNR 2022).

 

 
Statistik zum Anbau von Industriepflanzen
Cultivation of industrial crops by Anne Rödl (CC BY)
 
 A good overview of the structure of renewable raw materials grown in agriculture in Germany that are not used for food can be found in this report by the Fachagentur für Nachwachsende Rohstoffe (FNR 2022): 
https://www.fnr.de/ftp/pdf/berichte/22004416.pdf

 

Important plant groups

A distinction can be made on the basis of the mainly used organic ingredients of the plants:

  •     Sugar and starch-containing plants
  •     Protein-containing plants
  •     Oil-containing plants
  •     Lignocellulosic plants
  •     Medical plants, cosmetically used plants
However, plant waste and residues are also increasingly being recycled as materials or used to generate energy.
This article provides an overview of which agricultural waste and by-products can be used for biorefinery processes: https://www.frontiersin.org/articles/10.3389/fenrg.2020.00152/full
 
Bioabfall
Biowaste by Anne Rödl (CC BY)

Sugar

Plants synthesize simple sugars such as fructose and glucose directly from water and carbon dioxide with the help of sunlight during photosynthesis. Hydrogen is split off from the water, producing oxygen. The hydrogen is transferred to the carbon dioxide and fixed in a carbon compound.
 
Chemische Struktur von Saccharose
Saccharose von Anne Rödl (CC BY)
 

Important sugar-containing crops

 
Sugar cane and sugar beet are important sugar-containing crops that occupy considerable acreage worldwide.
1.9 billion tons of sugar cane and 270 million tons of sugar beet were produced worldwide in 2021 (FAO 2022). Important sugar cane growing countries are Brazil (38%) and India (22%), which together produce 60% of the total harvest (FAO 2022). In Brazil, around 45% of the sugar cane produced is used for the production of bioethanol (https://encyclopedia.pub/entry/17495).
World Bioethanolproduction 2021: 104,5 Mrd.l (https://www.isosugar.org/sugarsector/ethanol).  Of which a total of approx. 25 % from sugar cane (Hoang 2021, https://encyclopedia.pub/entry/17495)
Sugar beet is mainly grown in Russia, France, the USA, Germany and Turkey. They are mainly processed into sugar. Around 31.9 million tons of sugar beet were produced in Germany in 2021 (BLE 2022). However, some of the sugar beet grown is also used to produce ethanol or biogas. In Germany, around 1.3 million tons of sugar beet were used for ethanol production in 2021 and around the same amount for biogas production (FNR 2022).

The variety of products made from sugar beet is shown on this website.

Statistical data on the cultivation and use of sugar beet in Germany are summarized in this report by the Bundesanstalt für Ernährung und Landwirtschaft.
 
Zuckerrohr und Zuckerrübe
Sugar cane and sugar beet by Anne Rödl (CC BY) 
 


Starch

 

 
The plant quickly synthesizes starch from glucose, as this can be stored better and does not negatively affect the osmotic conditions. Starch consists of numerous glucose units that are linked via glycosidic bonds to form amylose or amylopectin.
 
Chemische Struktur von Stärke
Starch by Anne Rödl (CC BY)
 

Important starch-containing crops

 

 

Important crops containing starch, which account for a large proportion of the world's arable land, are the cereals maize, rice and wheat. 
 

Maize or corn 

Corn accounts for by far the largest share of the total amount of grain harvested and amounted to 1.2 billion tons worldwide in 2021. Around 31% of this quantity (approx. 384 million tons) was produced in the USA alone. Other important growing countries are China and Brazil. The cultivation of maize has expanded significantly in recent years, mainly due to its use for bioethanol and biogas production and as animal feed (FAO 2022). In the USA in particular, the majority of bioethanol produced is made from maize. The USA produced almost 57 billion liters of bioethanol in 2021, 93.8% of which was produced from corn (RFA 2022, p.25) 127 million tons of corn were used for this (USDA 2023, Feed Grains Yearbook). With a 55% share of global ethanol production, the USA is the largest producer of bioethanol. It can therefore be said that most of the bioethanol available worldwide is produced from maize.
 
Getreide
Grains by Anne Rödl (CC BY)
 
Rice
60% of the rice produced worldwide (2021: 787 million tons) is grown in China (27%), India (25%) and Bangladesh (7%). Rice is mainly used for food production.

Wheat
Wheat cultivation is not so strongly concentrated in individual producing countries. Only 40 % of the 787 million tons of wheat produced worldwide is produced in three countries: China (18 %), India (14 %) and Russia (10 %). The remaining 60% is produced in various other parts of the world. The quantities produced in China and India are also consumed there, while Russia, the USA, Canada, the EU and Ukraine export large parts of their production (Wolf et al. 2018)
Around 80% of wheat is used for food production, the rest for industrial applications or as animal feed.
In Germany, around 21.5 million tons of wheat were grown on 2.9 million hectares in 2021. Around 3% of this quantity was used for bioethanol production (FAOSTAT 2022 and FNR 2022).
 
Statistik: Weltweite Getreideproduktion 2000-2021
Works production of grains 2000-2021 by Anne Rödl (CC BY)

 
A detailed description of the chemical structure of plants containing sugar and starch as well as economically important representatives can be found in chapter 1.1 of the learning offer on future-oriented fuels on the HOOU platform.

Protein-containing plants

Proteins are amino acid molecules linked together via peptide bonds. Plants need nitrogen to build these.

Chemische Bausteine eines Proteins
Protein by Anne Rödl (CC BY)

 

 

Protein plants are mainly cultivated for their fruits or seeds with a high protein content and are used as food or animal feed. The most important crops are from the legume family, i.e. the papilionaceous plants. These include peas, beans, lentils and soybeans, which are usually referred to as pulses by the name of their superordinate family.

In 2021, pulses were grown on more than 95 million hectares. Beans (38%), chickpeas (16%) and black-eyed peas (16%), which are mainly grown in warmer regions in Africa, Latin America and Southeast Asia, accounted for the largest share. Almost 89 million tons of pulses were harvested from these areas worldwide in 2021. Beans (31%), chickpeas (18%), peas (14%) and black-eyed peas (10%) accounted for the largest shares of this harvest volume.

Hülsenfrüchte
Legumes by Anne Rödl (CC BY)

 

 

Oil-containing plants

Chemistry of oils and fats

Chemically speaking, oils and fats are esters of glycerol and three fatty acid units (triglyceride). They consist of 8 and 24 carbon atoms, hydrogen and oxygen.

Chemische Struktur von Fettsäuren
Fats by Anne Rödl, Joy Sheng (CC BY-NC-SA)

Oils and fats have the same general chemical structure, but oils are liquid under standard conditions (25 °C) and fats are solid. Oils are often of vegetable origin and fats of animal origin.

Oils and fats are mixtures of substances and do not have an exact melting point, but a melting range. They are insoluble in water.

They are referred to as saturated fatty acids if the carbon atoms are connected via single bonds.

 

Chemische Struktur der Palmitinsäure

Palmic acid by Anne Rödl (CC 0)



Unsaturated fatty acids contain single or multiple carbon double bonds.
Chemische Struktur der Ölsäure

Oleic acid by Anne Rödl (CC 0)

Oils and fats serve as energy sources or energy stores in plants, but also as solvents for fat-soluble vitamins. Plants often store oil in seeds and sometimes in the fruit flesh. It can be extracted from there.

Cultivation

The global area under oilseed crops in 2021 was around 338 million hectares, with a harvest volume of 1.2 billion tons.

Soybeans are not only a source of protein, but also a very important source of oil. Soy was grown on almost 130 million hectares worldwide in 2021 (FAOSTAT 2022), producing 373 million tons of soy.

The largest soybean-growing countries are Brazil, the USA and Argentina. Together, they produce over 80% of the world's soy.



Cultivation of oil-containing plants by Anne Rödl (CC BY)


As the oil plants differ greatly in their yields per hectare, a slightly different distribution emerges when looking at the quantities produced. Oil palms have a much higher specific yield than other oil plants and therefore account for the majority of the global harvest. Oil palms were cultivated on almost 29 million hectares worldwide, producing 416 million tons of oil fruits. The most important producing countries, together accounting for 87% of the global production volume, are Indonesia, Malaysia and Thailand (FAO 2022). Cotton seeds are mainly grown in China, India and the USA.

An even more detailed portrait of the most important oil plants and oil production can be found in chapter 1.2 of the Future Fuels learning offer on the HOOU platform. 

Lignocellulosic plants

Structure and composition

Starch is chemically converted by plants into other required reserve substances (fats and proteins) or secondary plant substances (tannins, alkaloids or essential oils) as required. These secondary plant substances are also very interesting for the bioeconomy and are therefore described in more detail in the chapter on plant-based medicines. Lignin is another such secondary plant substance. Perennial plants store it in their cell walls for stabilization. Because of this structural tissue of lignin and cellulose, they are referred to as lignocellulosic plants. The respective proportion of cellulose, hemicellulose and lignin depends on the species and the site conditions. The following table provides an overview of the composition and properties of important lignocellulosic plants.

Plant

Cellulose

Hemicellulose

Lignin

Ash

Water content

Heating value

 

(% DM)

(% DM)

(% DM)

(%)

(% FM)

(MJ/kg)

Miscanthus

44-57

16-30

8-22

1-9

3-49

15-21

Reed canary grass

26-39

17-28

4-5

2-13

7-65

16-20

Elephant grass

34-42

20-23

8-24

6-10

74

18

Common reed

34-38

21-28

19-23

3-8

16

14-15

Giant reed

31-39

21-35

18-23

3-6

36-42

14-15

Switchgrass

30-45

21-35

5-23

2-10

8-15

17-19

Sugarcane

34-42

29-43

19-21

2-12

6-50

17-18

Wheat straw

29-52

11-39

8-30

1-19

10-17

15-21

Maize straw

28-51

19-30

11-17

4-10

5-6

17-19

Softwood

35-83

8-42

12-43

1-6

0-63

16-24

Hardwood

28-50

18-39

13-28

0.2-5

2-48

15-21

Energy forestry (poplar, willow)

35-80

13-42

15-32

0.2-5

2-50

17-20

DM: Dry mass; FM: Fresh mass

Characteristics of lignocellulosic biomass by Anne Rödl (CC BY)


Forest wood

Forestry is an important supplier of economically significant quantities of lignocellulose raw materials. The world's forests produce wood as building and construction materials, for pulp and paper production and for energy generation. Wood is one of the most important bio-based resources used by humans and has been used for a wide variety of applications for thousands of years.

Humans manage a large proportion of the world's forests. Primeval forests as defined by the FAO still exist on 1.11 billion hectares, which is approx. 27 % of the total forest area (4.06 billion hectares), covering approx. 31 % of the global land area. The largest shares of forest areas are located in tropical (45 %) and boreal (27 %) zones of the earth (FAO 2020). The following figure shows the proportion of forest area in relation to the total area of the individual countries of the world.

Karte zur Waldbedeckung der Erde
Forest cover of the earth by Anne Rödl (CC BY)


In managed forests, humans manage the composition of tree species, the growth and quality of trees through various silvicultural interventions, such as:

  • Sowing, planting or promoting natural regeneration
  • Pruning, thinning or branching to reduce stand density and improve the quality of the remaining trees
  • Harvesting measures

The harvested logs can be divided into roundwood, industrial wood and pulpwood, which are primarily processed in the forestry industry. Not all parts of the tree are sold to the wood and paper processing industry. In most cases, weak tree parts, branches and the crown remain in the forest (residual forest wood) and serve as fertilizer for the forest soil after rotting. Increasingly, however, these assortments are also of interest to the energy industry. They are often used as firewood or are also of interest for biorefineries. However, care should be taken to ensure that sufficient residual wood remains in the forest for the supply of nutrients and for other ecological reasons (e.g. biodiversity).

The wood processing industry is strongly oriented towards softwood, as it grows predominantly straight and fast and has good properties for building and construction applications due to its lower density and simultaneous tensile and bending strength. Hardwood is often used in furniture construction and interior fittings. But even there, chipboard and fiberboard made from inferior softwood grades are increasingly being used for cost reasons and to reduce weight.

Around 1.4 billion m³ of softwood logs and 2.5 billion m³ of hardwood were harvested worldwide in 2020 (FAOSTAT 2023).

Around 117 million m3 of wood grows in German forests every year (bwi.info). To get a better idea of how much this is, a wooden cube is often used to visualize the growth of wood per second. For Germany, this cube would have an edge length of 1.55 meters.

Grafik Zuwachswürfel
Growth cube by Anne Rödl (CC BY)


In some regions, trees are mainly grown in plantations. In South America, plantations account for 99 % of planted forests (FAO definition of “Planted Forests”), whereas in Europe they account for just 6 % (FAO 2020). A plantation is usually established with only one tree species, at the same age and in a regular arrangement and is usually used for the rapid production of wood for fiber (for pulp production) or energy production (FAO definition).

Lignocellulosic biomass can also be supplied from agricultural or landcare waste streams, as well as from industry or demolition materials.

Lignocellulosic biomass is often considered a promising feedstock for biofuel production as it is an abundant source of organic material that is not in direct competition with food and feed. The lignocellulosic molecules can be cracked in an oxygen-free atmosphere by pyrolysis, they can be gasified and then liquefied using a Fischer-Tropsch synthesis, or they can be converted to sugar and then to alcohol.

Animal origin

By metabolizing their food, animals build up proteins and fats in their tissues, which in turn can serve as food for humans and animals. Animals also produce various products that are used by humans, such as honey, milk, eggs or wool. However, excretions or leftovers (skins or bones) are also used in a variety of ways. Raw materials of animal origin are mostly used in the food and animal feed industry. However, residues are also used as fertilizer or in biogas production. A relatively new branch is the production and use of insects as a source of protein for humans and animals. In 2021, for example, the EU approved mealworms as a “novel food”.

Current list of “novel foods” authorized in the EU

More information on insects as a source of protein can be found in Book 4.

Seeing the bigger picture

What are alternative proteins?

Alternative proteins are proteins produced by algae or fungi, come from insects or are cultivated from cells in the laboratory. They are used to produce meat substitutes, animal feed or as a milk alternative.

This branch of the bioeconomy is attracting more and more attention for various reasons. One reason is concern about the future food supply for a growing world population, another is ethical and environmental concerns about conventional meat and dairy products and the trend towards vegetarianism or veganism.

A start-up founded by graduates of Hamburg University of Technology uses bacteria to produce high-quality proteins for food and animal feed.

Microorganisms by www.europeana.eu (CC BY-SA)